Diels Alder Reaction Animation

Such conformations are called s cis the s referring to the single bond connecting the two double bonds.

Diels alder reaction animation. So we know that a diels alder reaction involves a concerted movement of six pi electrons. Interactive 3d chemistry animations of reaction mechanisms and 3d models of chemical structures for students studying university courses and advanced school chemistry hosted by university of liverpool. So if these pi electrons move into here before a bond between these two carbons these pi electrons move into here. Click the reaction arrow in sequence to view the 3d models and animations respectively.

Diels alder reaction between butadiene and maleic anhydride note the endo transition state. The s cis and s trans conformers of 13. When the same compound acts as both diene and dienophile in a diels alder reaction to couple it is a dimerization. In fulfilling objective 2 above you must recognize that the diels alder reaction is stereospecific.

The lewis acid chelates between the carbonyl groups of the dienophile which activates the alkene and locks the conformation so that the bulky isopropyl group blocks one face of the system in the s cis conformationcyclopentadiene undergoes diels alder reaction on the less hindered face. Finally note reaction b in the reading shows 13 cyclopentadiene reacting with another molecule of 13 cyclopentadiene. The driving force of the reaction is the formation of new s bonds which are energetically more stable than the p bonds. The diels alder reaction is a single step process so the diene component must adopt a cis like conformation in order for the end carbon atoms 1 4 to bond simultaneously to the dienophile.